Heat and Thermodynamics :: Problem 11

Problem 11: Determine the average value of Kinetic Energy of the particles of an ideal gas at 0oC and 50oC. Also find Kinetic Energy per mole of an ideal gas at these temperatures.

Solution:

Step: 1 Overview

From the derivation of Kinetic Energy from Kinetic Molecular Theory, we know that:
K.E=(3/2)kT
Above equation is the equation of Kinetic Energy of particles, to find the Kinetic Energy per mole, we use this formula:
K.E per mole = K.E per particle x NA
K.E per mole = (3/2)kTNA

Step: 2 Calculation

Kinetic Energy of particle at 0oC (273K):
K.E=(3/2)(1.38x10-23)(273)
K.E=5.65x10-21J (Ans)
Kinetic Energy of particle at 50oC (323K):
K.E=(3/2)(1.38x10-23)(323)
K.E=6.68x10-21J (Ans)
Kinetic Energy per mole at 0oC (273K):
K.E per mole =(3/2)(1.38x10-23)(273)(6.02x1023)
K.E per mole =3401.3 J/mole (Ans)
Kinetic Energy per mole at 50oC (323K):
K.E per mole =(3/2)(1.38x10-23)(323)(6.02x1023)
K.E per mole =4021.7 J/mole (Ans)
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